The ratio of E2−E1 to E4−E3 for the hydrogen atom is approximately equal to
E1=−13.6eV/atom E2=−3.4eV/atom E3=−1.51eV/atom E4=−0.85eV/atom Hence, E2−E1=−3.4+13.6=+10.2 E4−E3=−0.85+1.51=+0.66 Thus 10.20.66=15.45