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Question

The ratio of ground state energy of Li2+,He+ and H is :

A
1 : 2 : 3
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B
3 : 2 : 1
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C
1 : 4 : 9
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D
9 : 4 : 1
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Solution

The correct option is D 9 : 4 : 1
En = - RH ( Z2/n2)
ELi2+ = - RH ( 32/12), since, Z=3,n=1.
ELi2+ = - RH ( 9 )
EHe+ = - RH ( 22/12)
EHe+ = - RH ( 4 )
EH = - RH ( 12/12)
EH = - RH ( 1 )

The ratio of ground state energy of Li2+,He+ and H is 9:4:1.

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