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Question

The ratio of minimum wavelength of Lyman and Balmer series will be:

A
1.25
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B
0.25
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C
5
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D
10
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Solution

The correct option is B 0.25
The expression for wavelength is written as 1λ=RZ2[1n211n22]
The last line is a line of shortest wavelength or highest energy. When n2=, we get the last line wavelength.
1λ=RZ2[1n21]
λSeries limit=n21RZ2
For Lyman series, n1=1 and for Balmer series n1=2.
Therefore, λLymanλBalmer=n21Lymann21Balmer=1222=14=0.25

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