The raw materials used in solvay's process are as follows :
The solvay's ammonia soda process makes use of NaCl,NH3 and CaCO3 as the starting material
NaCl+CaCO3→Na2CO3+CaCl2
NH3 + H2O + CO2 + NaCl → NaHCO3 + NH4Cl
2NaHCO3 Heated−−−−−→ Na2CO3 + H2O + CO2