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Question

The reaction 2H2(g)+2NO(g)2H2O(g)+N2(g) is first order in H2 and second order in NO. The rate constant of the reaction at a certain temperature is 0.42M2s1. Calculate the rate when [H2]=0.015M and [NO] = 0.025M.

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Solution

The given reaction is :-
2H2+2NO2H2O+N2
(g) (g) (g) (g)

Given that, the reaction is first order in H2 & second order in NO. So,
Rate= K[H2]1[NO]2 (i)

Now, K is given as 0.42M2s1, [H2]=0.15×101M
[NO]=0.025M

So using these values in eqn(i)
Rate= 0.42×0.015×(0.025)2Ms1
=0.0000039375Ms1

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