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Question

The reaction (CH3)3CBr(CH3)3C++Br is an example of:

A
homolytic fission
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B
heterolytic fission
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C
cracking
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D
all of the above
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Solution

The correct option is B heterolytic fission
The reaction (CH3)3CBr(CH3)3C++Br is an example of heterolytic fission.

The C-Br bond breaks asymmetrically and results in the formation of tert butyl carbocation and bromide anion.

This type of fission is observed for the bonds between two atoms with significant difference in the electronegativity.

In case of homolytic fission, the bond breaks symmetrically and results in the formation of free radicals. It is observed for the bonds between two atoms with same electronegativity.

For example, the homolytic fission in ethane forms two methyl free radicals.

CH3CH32CH3

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