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Question

The reaction in which H>U is

A
N2(g)+O2(g)2NO(g)
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B
CaCO3(s)CaO(s)+CO2(g)
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C
N2(g)+3H2(g)2NH3(g)
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D
CH4(g)+2O2(g)CO2(g)+2H2O(l)
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Solution

The correct option is B CaCO3(s)CaO(s)+CO2(g)
Relation of H with U is given by the formula:
H=U+ngRT
ng = change in number of moles of gas particles
Hence, H>U when ng>0
This happens only in:
CaCO3(s)CaO(s)+CO2(g)
ng=1

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