The reaction is given below, the rate constant for disappearance of A is 7.48×10−3sec−1. The time required for the total pressure in a system containing A at an initial pressure of 0.1 atm to rise to 0.145 atm is: 2A(g)→4B(g)+C(g)
A
0.80 min
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B
0.567 min
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C
0.433 min
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D
0.344 min
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Solution
The correct option is A 0.80 min Its a first order reaction and for this, kt=2.303log(aa−x)
Here, 2A(g)→4B(g)+C(g) P - - P-2x 4x x
So here, P-2x+4x+x= 0.145 From given condition 2x is 0.03 and t=2.303klog(pp−2x)=47.63seconds=0.80 min.