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Question

The reaction of acetaldehyde in the presence of Al(OC2H5)3 produces:

A
CH3CH(OH)CH2CHO
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B
CH3CH=CHCHO
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C
CH3COOC2H5
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D
no reaction
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Solution

The correct option is B CH3COOC2H5
All aldehydes in the presence of aluminium ethoxide Al(OC2H5)3 can be simultaneously oxidized to acid and reduced to alcohols to form esters. This is called Tischenko reaction, it is like a Cannizzaro reaction.
CH3CHOAl(OC2H5)3−−−−−−CH3COOC2H5

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