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Question

The reaction of propene with HOCl proceeds via the addition of:

A
H+ in first step
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B
Cl+ in first step
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C
OH in first step
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D
Cl+ and OH in single step
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Solution

The correct option is B Cl+ in first step

In the case of hypochlorous and hypobromous acids (HOX), these weak Brønsted acids (pKa's ca. 8) do not react as proton donors; and since oxygen is more electronegative than chlorine or bromine, the electrophile will be a halide cation.

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