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Question

The reaction which is taking place in nickel- cadmium battery can be represented by which of the following equation?

A
Cd+NiO2+2H2OCd(OH)2+Ni(OH)2
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B
Cd+NiO2+2OHNi+Cd(OH)2
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C
Ni+Cd(OH)2Cd+Ni(OH)2
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D
Ni(OH)2+Cd(OH)2Ni+Cd+2H2O
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Solution

The correct option is A Cd+NiO2+2H2OCd(OH)2+Ni(OH)2
Due to their low internal resistance and the very good current conducting properties , Ni-Cd cells can supply extremely high currents and can be recharged rapidly
The reactions involved in Nickel-Cadmium battery are,
At Anode: Cd(s)+2OH(aq)Cd(OH)2(s)+2e
At cathode: NiO2(s)+2H2O(l)+2eNi(OH)2(s)+2OH(aq)
Overall reaction: Cd(s)+NiO2(s)+2H2O(l)Cd(OH)2(s)+Ni(OH)2(s)

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