The reaction, X⟶Y (Product), follows first order kinetics. In 40 minutes, the concentration of X changes from 0.1M to 0.025M, then the rate of reaction when concentration of X is 0.01M is:
A
1.73×10−4M/min
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B
3.47×10−5M/min
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C
3.47×10−4M/min
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D
1.73×10−5M/min
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Solution
The correct option is B3.47×10−4M/min ln(0.10.025)=ktk=ln(4)40SoforA=0.01MThus,Rate=k[A]=ln(4)40(0.01)=3.47×10−4M/min