The reactivities of these ions in azo-coupling reactions will be in the order:
A
3<1<4<2
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B
1<4<2<3
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C
1<2<3<4
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D
3<1<2<4
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Solution
The correct option is C1<2<3<4 In azo-coupling, the diazonium ion should be more electrophilic for more reactivity. Presence of electron-withdrawing groups increase the reactivity.
Considering these factors, the order of reactivity should be: