The reagent which can distinguish $[C r (N H_{3})_{5} B r] C l$ and $[C r (N H_{3})_{5} C l] B r$ and the type of isomerism exhibited by these two complexes are :

B a C l_{2}

and ionisation isomerism

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A g N O_{3}

and ionisation isomerism

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A g N O_{3}

and coordination isomerism

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B a C l_{2}

and linkage isomerism

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Solution

The correct option is B $A g N O_{3}$ and ionisation isomerism
$[C r (N H_{3})_{5} B r] C l$ and $[C r (N H_{3})_{5} C l] B r$ can be distinguished by $A g N O_{3}$ and isomerism shown is ionisation isomerism.
$A g N O_{3}$ reacts with $C l^{-}$ atom in the outer coordination sphere to form white precipitate of $A g C l$ . When $B r^{-}$ is in the outer coordination sphere, a pale yellow precipitate of $A g B r$ forms.

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Q. Define linkage and ionisation isomerism?

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The reagent which can distinguish [Cr(NH3)5Br]Cl and [Cr(NH3)5Cl]Br and the type of isomerism exhibited by these two complexes are :

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