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Question

The reagents that can be used to identify Fe3+ is :

A
K4Fe(CN)6
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B
KCNS
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C
CH3COO
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D
All of the above
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Solution

The correct option is B All of the above
(i). F(III) ions give deep blue colour with potassium ferrocyanide.
3K4[Fe(CN)6]+4FeCl3Fe4[Fe(CN)6]3prussian blue+12KCl
(ii). Fe(III) ion gives a blood red colouration with thiocyanate ions.
FeCl3+3NH4SCNFe(SCN)3red colour+3NH4Cl

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