The reduction potential of hydrogen electrode when placed in a buffer solution is found to be 0.413V. The part of the buffer is:
A hydrogen electrode placed in a buffer solution of CH3COONa and CH3COOH in the ratios x:y and y:x has electrode potential values E1 volts and E2 volts respectively at 250C . The pKa value of acetic acid is :
[E1and E2 are oxidation potentials]