The relationship between enthalpy and internal energy change is
A
ΔU=ΔH+PΔV
No worries! We‘ve got your back. Try BYJU‘S free classes today!
B
ΔH=ΔU+PΔV
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
C
ΔH=ΔU−PΔV
No worries! We‘ve got your back. Try BYJU‘S free classes today!
D
PΔV=ΔU+ΔH
No worries! We‘ve got your back. Try BYJU‘S free classes today!
Open in App
Solution
The correct option is BΔH=ΔU+PΔV
Chemical reactions are generally carried out at constant pressure (atmospheric pressure) so it has been found useful to define a new state function Enthalpy (H) as :
H=U+PV ( By definition )
ΔH=ΔU+Δ(PV)
ΔH=ΔU+PΔV (at constant pressure) combining with first law.