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Question

The relative basics strenghts of NH3,CH3NH2 and NF3 are in the order:

A
CH3NH2>NH3>NF3
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B
NF3>CH3NH2>NH3
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C
NH3>CH3NH2>NF3
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D
NF3>CH3NH2=NH3
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Solution

The correct option is A CH3NH2>NH3>NF3
CH3 group is electron donating group.
F is electron withdrawing group.
So CH3NH2 is more basic. NH3 is more basic than NF3 because H is not a withdrawing group. NF3 is less basic.
Basic nature order= CH3NH2>NH3>NF3

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