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Question

The relative extent to which the various orbitals penetrate the electron clouds of other orbitals is:

A
s>p>d>f
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B
s<p<d<f
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C
s<d<p<f
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D
d<s<p<f
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Solution

The correct option is B s>p>d>f
Electron in s-orbital is closer to nucleus than electron in p-orbital and electron in p-orbital is closer to nucleus than electron in d-orbital and so on. So,more energy is requried to remove electron from s-orbital than electron in p-orbital in spite of both having same principal quantum number. Similarly, p orbital will require more energy than d-orbital. this is called penetrating effect. it decreases in order s>p>d>f

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