The relative lowering of vapour pressure caused by dissolving 71.3 g of a substance in 1000 g of water is 7.13×10−3. The molecular mass of the substance is :
The relative vapour pressure caused by dissolving a substance in water is given as,
P0−PsP0=⎛⎜ ⎜ ⎜⎝wmwm+WM⎞⎟ ⎟ ⎟⎠
7.13×10−3=⎛⎜ ⎜ ⎜⎝71.3m71.3m+100018⎞⎟ ⎟ ⎟⎠
m=178.72
Thus, the molecular mass of the substance is 178.72.
Hence, the correct option is A