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Question

The relative rate of the acid-catalyzed dehydration of the following alcohols would be

A
(III) > (II) > (I)
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B
(II) > (III) > (I)
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C
(I) > (III) > (II)
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D
(III) > (I) > (II)
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Solution

The correct option is B (II) > (III) > (I)

Since dehydration involves the formation of carbocation in rate determining step, more the stability of carbocation, more will be rate of acid catalysed dehydration.
3>2>1 - stability of carbocation


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