The relative rate of the acid-catalyzed dehydration of the following alcohols would be
A
(III) > (II) > (I)
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B
(II) > (III) > (I)
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C
(I) > (III) > (II)
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D
(III) > (I) > (II)
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Solution
The correct option is B(II) > (III) > (I)
Since dehydration involves the formation of carbocation in rate determining step, more the stability of carbocation, more will be rate of acid catalysed dehydration. 3∘>2∘>1∘ - stability of carbocation