The correct option is C 180o
Resultant of two vectors is given by parallelogram law of vector addition. As per this law, the resultant vector is R=√(A2+B2+2ABcosθ). Here A and B are the two vectors and θ is the angle between them. You can see that R will be minimum when θ is equal to 180o that is when the 2 vectors are antiparallel to each other