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Question

The SS bond energy is:

ΔHof(EtSEt)=147kJ/mol
ΔHof(EtSSEt)=202kJ/mol
ΔHofS(g)=+223kJ/mol

A
168 kJ
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B
126 kJ
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C
278 kJ
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D
575 kJ
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Solution

The correct option is D 278 kJ
C2H5SC2H5+S(s)C2H5SSC2H5
ΔHreaction=ΔHof(products)+ΔHof(reactants)
=(202)(147)=55kJ
ΔHreaction=BEreactantsBEproducts
55= Heat of sublimation or enthalpy of atomisation of sulphurBE(SS)
55=223BE(SS)
BE(SS)=223+55=278kJ

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