The correct option is A 4−O−β−D- glucopyranosyl-D-glucose.
Cellobiose, the disaccharide obtained by partial hydrolysis of cellulose, consists of two D-glucopyranoses joined by a 1,4,-beta-glycoside bond. Cellobiose is reducing sugar, because the anomeric carbons on the right-hand sugar are part of a hemiacetal.
Cellobiose : 4-O--D-Glucopyranosyl-D-glucose. Thus, option A is correct.
The other options are not related to the cellobiose. Thus, other options are incorrect.