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Question

The screening effect of d-electrons is:


A

Equal to the p-electrons

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B

More than p-electrons

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C

Same as f-electrons

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D

Less than p-electrons

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Solution

The correct option is D

Less than p-electrons


For this let's discuss penetration effect.

Penetration power can be simply phrased as closeness to the nucleus.

Within a principle quantum number, s is closer to the nucleus to the nucleus than p, d and f.

The correct order of orbitals in a given shell for the penetration effect is s >p > d > f.

Screening effect, also known as the shielding effect, reduces the effect of the nucleus on the outer electrons, i.e., inner electrons act as a shield and reduce the electrostatic interaction between the nucleus and outer most electrons.

Now as we know from the penetration effect that s and p are closer to the nucleus than d, therefore they will shield the d electrons. But within a shell d electrons will not be able to shield the p electrons.

This implies screening effect of d-electrons is less than p-electrons.


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