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Question

The shape of IF6 is:

A
trigonally distorted octahedron
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B
pyramidal
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C
octahedral
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D
square antiprism
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Solution

The correct option is A trigonally distorted octahedron
The shape of IF6 is trigonally distorted octahedron. The central iodine atom has 7 valence electrons. It gains one electron from negative charge. Out of 8 valence electrons, 6 are involved in formation of 6 IF bonds and one lone pair of electrons is present. 6 F atoms are present at 6 corners of distorted octahedron. The lone pair of electrons distorts the octahedral shape due to electron electron repulsion.

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