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Question

The short wavelength limit for the Lyman series of the hydrogen spectrum is 913.4oA. Calculate the short wavelength limit for Balmer series of the hydrogen spectrum.

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Solution

Rydberg formula for wavelength for the hydrogen spectrum is given by
1λ=R[1/n211/n22]
For short wavelength of Lyman series, 1913.4=R[1/121/2]
or R=(1/913.4)A1
For short limit of wavelength for Balmer series, 1λb=R[1/221/2]
or λb=4/R=4(913.4)=3653.6Ao=365.36nm

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