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Question

The slope of Arrhenius plot (ln k v/s 1T) of first order reaction is 5×103 K. The value of Ea of the reaction is. Choose the correct option for your answer. [Given R=8.314 JK1 mol1]

A
83 kJ mol1
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B
41.5 kJ mol1
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C
83.0 kJ mol1
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D
166 kJ mol1
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Solution

The correct option is B 41.5 kJ mol1
Arrhenius equation

k=AeEa/RT

lnk=lnA+lneEa/RT

lnk=lnAEaR(1T) .......(1)

Slope of lnk vs1T curve,

m=EaR

5×103=EaR

Ea=5×103×8.314 J/mol

41.57×103 J/mol

=41.5 kJ/mol

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