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Question

The sodium extract on acidification with acetic acid and then adding lead acetate solution gives a black precipitate. The organic compound contains

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Solution

Analysing the reaction

The sodium fusion extract is acidified with acetic acid and lead acetate is added to it. A black precipitate of lead sulphide indicates the presence of sulphur in organic compounds.

Na2S+Pb(CH3COO)2
Lead acetate
CH3COOH
PbS()+2CH3COONa
Black precipitate.

So, the organic compounds contain sulphur.

Hence, the correct answer is Option (c).

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