When AgNO3 solution is added to KI solution
AgNO3(aq)+KI(aq)→AgI(s)↓+AgNO3(aq)
AgI gets precipitated.
The precipitated silver iodide adsorbs iodide ions (I−) from the dispersion medium and negatively charged colloidal sol is formed AgI/I−
When KI solution is added to AgNO3 solution
AgNO3(aq)+KI(aq)→AgI(s)↓+AgNO3(aq)
AgI gets precipitated.
The precipitated silver iodide adsorbs Ag+ions from the dispersion medium and positively charged colloidal sol is formed AgI/Ag+
Option (b) is correct