The solubility of a solute is 35 at and 25 to . If 200 g of solvent is made to saturate with the solute at , what is the amount of precipitate formed at ?
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Solution
The amount of solute dissolved in a definite quantity of a solvent depends upon the nature of the solute & nature of the solvent.
The maximum amount of a solute in grams , which can dissolve in 100g of a solvent at a given temperature is called solubility.
For most of the substances, solubility increases with the increase in temperature .
It is given that solubility of a solute at = 35 and solubility of the solute at = 25
100 g of the solvent a t dissolves 35 g of the solute to get a saturated solution
In 200 g of the solvent at dissolve ( 2 x 35 ) = 70g of solute to get a saturated solution.
At , 100g of solvent dissolves 25 g of solute.
At 200 g of solvent dissolves ( 25 x 2 ) 50 g of solute .
The extra salt is precipitated when temperature decreases .
The solute precipitated is 70 - 50 = 20 g at .
Therefore the amount of precipitate formed at is 20 g solute .