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Question

The solubility of a solute is 35 at 60oC and 25 to 30oC. If 200 g of solvent is made to saturate with the solute at 60oC, what is the amount of precipitate formed at 30oC?


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Solution

  1. The amount of solute dissolved in a definite quantity of a solvent depends upon the nature of the solute & nature of the solvent.
  2. The maximum amount of a solute in grams , which can dissolve in 100g of a solvent at a given temperature is called solubility.
  3. For most of the substances, solubility increases with the increase in temperature .
  4. It is given that solubility of a solute at 60oC = 35 and solubility of the solute at 300C = 25
  5. 100 g of the solvent a t 60oC dissolves 35 g of the solute to get a saturated solution
  6. In 200 g of the solvent at 60oC dissolve ( 2 x 35 ) = 70g of solute to get a saturated solution.
  7. At 300C, 100g of solvent dissolves 25 g of solute.
  8. At 30oC 200 g of solvent dissolves ( 25 x 2 ) 50 g of solute .
  9. The extra salt is precipitated when temperature decreases .
  10. The solute precipitated is 70 - 50 = 20 g at 30oC.

Therefore the amount of precipitate formed at 30oC is 20 g solute .


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