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Question

The solubility of haloalkanes/haloarenes is highest in

A
Water
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B
Non-polar solvents
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C
Polar Solvents
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D
Acetic acid
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Solution

The correct option is B Non-polar solvents
Energy required to overcome attractions between R-X molecules​ and energy required to break H-bond between water molecule is greater than energy released when new​ bonds are setup between R-X​ and water​. Hence, haloalkanes are​ slightlly soluble in water.​
Energy required to overcome attractions between R-X molecules​ and energy required to overcome interactions between organic solvents​ is nearly same as energy released when new​ bonds are setup between R-X​ and organic solvents​. Hence, haloalkanes are​ highly soluble in organic solvents.​

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