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Question

The solubility order of the chlorides of the alkali metals is

A
NaCl > KCl > RbCl > CsCl
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B
CsCl > RbCl > KCl > NaCl
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C
KCl > NaCl > RbCl > CsCl
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D
Cs Cl > RbCl > NaCl > KCl
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Solution

The correct option is A NaCl > KCl > RbCl > CsCl
Solubility of chlorides of alkali metal decrease down the group.Stability of alkali metal chlorides decreases down the group. lattice enthalpy of ionic solid of cation of same valency having same anion decreases. It's due to down the group size of cation increases so attractive force between anion and cation decreases.
Hence Option A iscorrect answer

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