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Question

The species among the following having the highest electron affinity is:

A
O
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B
F
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C
Cl
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D
O
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Solution

The correct option is A O
Fluoride and chloride ions have a complete octet configuration. Hence, they are not ready to accept an electron. When adding one more electron to the uninegative oxygen anion, electron-electron repulsion will occur and makes the reaction endothermic.

Hence, the oxygen atom has the highest electron affinity among other given options.

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