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Question

The specific conductance of a saturated solution of AgCl is found to be 1.86×106ohm1cm1 and that of water is 6×108ohm1cm1. The solubility of AgCl given thatλ0AgCl=(137.2 ohm1cm1 is ×105M)

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Solution

κAgCl=κAgCl(solution)κH2O
=1.86×1066×108=1.8×106ohm1cm1
λ0AgCl=k×1000s
s=1.31×105M

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