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Question

The specific rate constant of the decomposition of N2O5 is 0.008min1. The volume of O2 collected after 20 minute is 16 mL. The volume in ml that would be collected at the end of reaction. NO2 formed is dissolved in CCl4 is

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Solution

k=0.008/min,t=20min,x=16mL
The unit of the rate constant indicates that it is a first order reaction.
k=2.303tlogaax
0.008=2.30320logaa16
logaa16=1.17
a=108.23
Henc, 108.23 mL would b collectd at the end of reaction.

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