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Question

The spin magnetic moment of cobalt in Hg[Co(SCN)4] is

A
3
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B
8
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C
15
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D
24
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Solution

The correct option is C 15
The spin only magnetic moment is given by the formula μeff=n(n+2)B.M..

The cobalt atom in Hg[Co(SCN)4] carries +2 charge and has 3d7 as the outer electronic configuration.

Here Hg shows +2 oxidation state and the compound is known as Mercuric tetrathiocyanatocobaltate(II).

It contains three unpaired electrons.

For three unpaired electrons, the expression becomes μeff=3(3+2)B.M.=15B.M.

Therefore, option C is correct.

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