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Question

The spin only magnetic moment of [CoF6]3 is:

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Solution

The complex [CoF6]3 is an octahedral complex.
Here the oxidation state of Co is +3
Thus the elctronic configuration of Co3+=[Ar]3d6
So, according to crystal field splitting theory, the electronic configuration in d orbital will be t42ge2g
So number of unpaired electrons is = 4
Again spin only magnetic moment is given by, n(n+2),
Where n =number of unpaired electron
So, the spin only magnetic moment of [CoF6]3+=4(4+2)=4.89

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