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Question

The spin only magnetic moment of [ZCl4]2 is 3.87 BM where Z is:

A
Mn
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B
Ni
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C
Co
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D
Cu
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Solution

The correct option is C Co
μ=3.87=n(n+2)n=3

[ZCl4]2; oxidation state of Z is +2

No. of unpaired electrons is 3.

Hence, Z2+=d7

So, element is Co.

674227_631430_ans_ad6869168a794e4ebbd001d1713aeb5e.PNG

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