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Question

The spontaneous cell reaction (i.e., redox reaction) in galvanic cell is derived by:

A
reduction reaction at right electrode - reduction reaction at left electrode
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B
oxidation reaction at left electrode + reduction reaction at right electrode
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C
reduction reaction at right electrode + reduction reaction at left electrode
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D
oxidation reaction at left electrode - oxidation reaction at right electrode
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Solution

The correct options are
A reduction reaction at right electrode - reduction reaction at left electrode
B oxidation reaction at left electrode + reduction reaction at right electrode
D oxidation reaction at left electrode - oxidation reaction at right electrode

We know that in any Galvanic Cell, Oxidation occurs at Anode (Left Hand Electrode) and Reduction occurs at Cathode (Right Hand Electrode).

Hence, EMF of the Cell will be given as:

E0cell=E0SRP,cathode + E0SOP,anode

E0cell=E0SRP,cathode - E0SRP,anode

E0cell=E0SOP,anode - E0SOP,cathode
Hence, option C is incorrect and all other options are the answers.

343171_184296_ans_892f8d6a58114cdeba5e454627cf7dd8.png

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