The stability of the following alkali metal chlorides follows the order:
KCl > CsCl > NaCl > LiCl
More the –ve value of heat of formation, greater is the stability of the compound due to lower magnitude of potential energy.
Δ Hf = -97.7. -98.6, -103.5, -104.2 Kcal for LiCl, NaCl, CsCl, KCl