The standard electrode potential of a metal ion Ag - Ag- and metal insoluble salt anion Ag - AgCl - Cl- are related as-

The correct option is B E^⊖_Cl^⊖ | AgCl | Ag = E^⊖_Ag^⊕ | Ag + RT/F ln K_sp Cathode #160;: AgCl + e^ → #160; Ag + Cl^⊖ Anode #160;: ...

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Valence Bond Theory

The standard ...

Question

The standard electrode potential of a metal ion $(A g | A g^{\oplus}$ and metal insoluble salt anion $(A g | A g C l | C l^{⊖})$ are related as:

E_{A g^{\oplus} | A g}^{⊖} | = E_{C l^{⊖} | A g C l | A g}^{⊖} + \frac{R T}{F} l n K_{s p}

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E_{C l^{⊖} | A g C l | A g}^{⊖} = E_{A g^{\oplus} | A g}^{⊖} + \frac{R T}{F} l n K_{s p}

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E_{A g^{\oplus} | A g}^{⊖} = E_{C l^{⊖} | A g C l | A g}^{⊖} + \frac{R T}{F} l n \frac{[C l^{⊖}]}{K_{s p}}

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E_{C l^{⊖} | A g C l | A g}^{⊖} = E_{A g^{\oplus} | A g}^{⊖} + \frac{R T}{F} l n \frac{K_{s p}}{[C l^{⊖}]}

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C l^{⊖} | A g C l | A g

A g^{⊖} | A g

E_{A g^{⊖} | A g}^{⊖} = E_{C l^{⊖} | A g C l | A g}^{⊖} + \frac{R T}{F}

K_{s p}

C l^{-} | A g C l | A g

A g^{+} | A g

E_{A g + | A g}^{o} = E_{C l^{-} | A g C l | A g}^{o} + \frac{R T}{F} l n K_{s p} (A g C l)

A g C l_{(s)} + e^{-} \to A g_{(s)} + C l_{(a q)}^{-}

E^{⊖} = 0.22

A g_{(a q)}^{+} + e^{-} \to A g_{(s)}; E^{⊖} = 0.80

A g C l

A g {C l}_{(s)} + e^{-} \to {A g}_{(s)} + {C l}_{(a q)}^{-}; E = 0.22 V

{A g}_{(a q)}^{+} + e^{-} \to {A g}_{(s)}; E = 0.80 V

A g C l

298 K

A g^{+} (a q) + e^{-} \to A g (s)

E^{0} = + 0.799 V

A g C l (s) + e^{-} \to A g (s) + C l^{-} (a q)

E^{0} = + 0.222 V

1.743 \times 10^{- 10}

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