The standard electrode potential of two half cells are given below- Ni+2+2e−⟶Ni;E0=−0.25V Zn+2+2e−⟶Zn;E0=−0.77V The voltage cell formed by combining the two half cell would be:
A
-1.02 V
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B
+0.52 V
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C
+1.02 V
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D
-0.52 V
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Solution
The correct option is B +0.52 V
Given,
Ni2++2e−⟶Ni;E01=−0.25V
Zn2++2e−⟶Zn;E02=−0.77V
E01−E02⇒Ni2++2e−+Zn→Ni+Zn2++2e−
Ni2++Zn→Ni+Zn2+
Er×n=E01−E02
=(−0.25)−(0.77)
=0.52 Volts
the voltage cell formed by combing two half cell would be 0.52 Volts.