The standard emf of galvanic cell involving 3 moles of electrons in its redox reaction is 0.59V. The equilibrium constant for the reaction of the cell is:
A
1025
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B
1020
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C
1015
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D
1030
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Solution
The correct option is D1030 The standard emf of a galvanic cell involving 3 moles of electrons in its redox reaction is 0.59V.
Eocell=0.59V
n=3
The equilibrium constant for the reaction of the cell is given by the expression
lnK=nFEocellRT
lnK=3×96500×0.598.314×298
lnK=68.9
K≈1030
The equilibrium constant for the reaction of the cell is 1030.