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Question

The standard emf of galvanic cell involving 3 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the reaction of the cell is:

A
1025
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B
1020
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C
1015
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D
1030
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Solution

The correct option is D 1030
The standard emf of a galvanic cell involving 3 moles of electrons in its redox reaction is 0.59V.
Eocell=0.59V

n=3

The equilibrium constant for the reaction of the cell is given by the expression
lnK=nFEocellRT

lnK=3×96500×0.598.314×298

lnK=68.9

K1030

The equilibrium constant for the reaction of the cell is 1030.

Hence, the correct answer is option D.

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