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Question

The standard molar heat of formation of ethane, CO2 and water (l) are respectively 21.1, 94.1 and 68.3Kcal. The standard molar heat of combustion of ethane will be:

A
-372 Kcal
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B
- 162 Kcal
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C
- 240 Kcal
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D
-183. 5 Kcal
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Solution

The correct option is D -372 Kcal
Solution:- (A) 372kcal
Combustion of ethane-
C2H6(s)+72O2(g)2CO2(g)+3H2O(l)
ΔH0=ΔH0f(product)ΔH0f(reactant)
ΔH0=(2×(94.1)+3×(68.3))(21.1+0)
ΔH0=393.1+21.1=372kcal
Hence the standard molar heat of combustion will be 372kcal.

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