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Question

The standard reduction potentials of Cu+2, Ag+, Hg+2 and Mg+2 are 0.34V, +0.80V ,+0.79V and 2.37V respectively. With increasing voltage, the sequence of deposition of metals on the cathode from an aqueous solution containing all those ion is:


A
Ag, Hg, Mg, Cu
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B
Cu, Hg, Ag, Mg
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C
Ag, Hg, Cu, Mg
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D
Cu, Hg, Mg, Ag
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Solution

The correct option is A Ag, Hg, Cu, Mg
As voltage increases, the metal which reduces more easily gets deposited first. SRP value are directly related to each reduction
Order of deposition is decreasing order of SRP value
Hence, order is first Ag, then Hg then Cu and then Mg

Correct option is C

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