The standard reduction potentials of Cu+2, Ag+, Hg+2and Mg+2are 0.34V, +0.80V ,+0.79V and 2.37V respectively. With increasing voltage, the sequence of deposition of metals on the cathode from an aqueous solution containing all those ion is:
A
Ag, Hg, Mg, Cu
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B
Cu, Hg, Ag, Mg
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C
Ag, Hg, Cu, Mg
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D
Cu, Hg, Mg, Ag
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Solution
The correct option is A Ag, Hg, Cu, Mg As voltage increases, the metal which reduces more easily gets deposited first. SRP value are directly related to each reduction ∴ Order of deposition is decreasing order of SRP value Hence, order is first Ag, then Hg then Cu and then Mg