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Question

The stopcock containing two bulbs of volume 5 litre and 10 litre containing an ideal gas at 9 atm and 60 atm respectively is opened. What is the final pressure in atm if the temperature remains the same?

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Solution

Total volume =5L+10L=15L
Number of moles in 5 L bulb n=PVRT=9atm×5LRT=45RTmoles
Number of moles in 10 L bulb n=PVRT=60atm×10LRT=600RTmoles
Total number of moles n"=n+n=45RT+600RT=645RT
The final pressure P=n"RTV=645RTRT15=43atm

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