The stopcock containing two bulbs of volume 5litre and 10litre containing an ideal gas at 9atm and 60 atm respectively is opened. What is the final pressure in atm if the temperature remains the same?
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Solution
Total volume =5L+10L=15L Number of moles in 5 L bulb n=PVRT=9atm×5LRT=45RTmoles Number of moles in 10 L bulb n′=PVRT=60atm×10LRT=600RTmoles Total number of moles n"=n+n′=45RT+600RT=645RT The final pressure P=n"RTV=645RTRT15=43atm