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Question

The strongest acid in the following compounds is:

A
phenol
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B
p-cresol
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C
m-nitrophenol
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D
p-nitrophenol
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Solution

The correct option is B p-nitrophenol
o-nitro phenol participates in intra-molecular Hbonding, which makes it less acidic than p-nitro phenol. Since acidic strength depends on the stability of negative ion after removal of acidic H, NO2 group in o and p position provides M effect as the negative charge delocalizes.

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