The structural unit present in pyrosillicates is:
Pyrosilicates are silicates which contain Si2O6−7 . They are formed by joining two tetrahedral Si2O4−4 . When two Si2O4−4 are joined, there is removal of one oxygen atom and the two units join at the corner oxygen atom. Example is thortveitite, Sc2Si2O7 . The structure of pyrosilicate is: