Solid PCl5→[PCl4]++[PCl6]−
Hybridisation of [PCl4]+=sp3
Hybridisation of [PCl6]−=sp3d2
Solid PBr5→[PBr4]++[Br]−
Hybridisation of [PBr4]+=sp3
Solid N2O5→[NO+2]++[NO+3]−
Hybridisation of [NO+2]=sp
Hybridisation of [NO+3]−=sp2
Hence, the sum of all sp3, sp2 and sp units present in solid PCl5, solid PBr5, and solid N2O5 is 4.